The Man of Steel, although not the main character, was central to the early Target exclusive stealth release JLA Adventures: Trapped in Time. Supes was the inspiration for the 31st century's Legion of Superheroes, and his deletion from history resulted in the paradox remedying deletion of the Justice League. In addition, this movie is notable in edging out Justice League: War in introducing the trunkless new 52 inspired Superman design to animation... well if you don't count his few seconds in the Superman 75th tribute short. In an "Ape-raham Lincoln" like twist (see Tim Burton's Planet of the Apes) the movie ended on a spoiler where the inspirational Kal-El was upstaged by a villainous Luther. To be continued... I hope.
Check back next week for another chapter in The Super History of Superman.